Most of the sulfur used in the United States is chemically synthesized from hydrogen sulfide gas recovered from natural gas wells. In the first step of this synthesis, called the Claus process, hydrogen sulfide gas is reacted with dioxygen gas to produce gaseous sulfur dioxide and water.Suppose a chemical engineer studying a new catalyst for the Claus reaction finds that 250. liters per second of dioxygen are consumed when the reaction is run at 290.°C and the dioxygen is supplied at 0.52atm. Calculate the rate at which sulfur dioxide is being produced. Give your answer in kilograms per second. Round your answer to 2 significant digits.
Question
Most of the sulfur used in the United States is chemically synthesized from hydrogen sulfide gas recovered from natural gas wells. In the first step of this synthesis, called the Claus process, hydrogen sulfide gas is reacted with dioxygen gas to produce gaseous sulfur dioxide and water.Suppose a chemical engineer studying a new catalyst for the Claus reaction finds that 250. liters per second of dioxygen are consumed when the reaction is run at 290.°C and the dioxygen is supplied at 0.52atm. Calculate the rate at which sulfur dioxide is being produced. Give your answer in kilograms per second. Round your answer to 2 significant digits.
Solution
To solve this problem, we need to follow these steps:
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Write the balanced chemical equation for the Claus process:
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Determine the molar volume of dioxygen gas at the given conditions using the Ideal Gas Law: Where:
- is the pressure (0.52 atm)
- is the volume (250 L/s)
- is the ideal gas constant (0.0821 L·atm/(K·mol))
- is the temperature in Kelvin (290°C + 273 = 563 K)
Rearrange the Ideal Gas Law to solve for (moles of ):
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Use stoichiometry to find the rate of sulfur dioxide production: From the balanced equation, 1 mole of produces 1 mole of . Therefore, the rate of production is the same as the rate of consumption:
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Convert moles of to mass: The molar mass of is:
Therefore, the mass of produced per second is:
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Convert grams per second to kilograms per second:
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Round to 2 significant digits:
So, the rate at which sulfur dioxide is being produced is approximately 0.18 kilograms per second.
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