QuestionNo.13(Single Correct) A+ A-Marks : 4.00/ 1.00Which of the following keto gives most stable enol during tautomerism ?
Question
QuestionNo.13(Single Correct) A+ A-Marks : 4.00/ 1.00Which of the following keto gives most stable enol during tautomerism ?
Solution
To determine which keto form gives the most stable enol during tautomerism, we need to consider the factors that contribute to stability.
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Resonance: Look for keto forms that have resonance structures that stabilize the enol form. Resonance occurs when electrons can delocalize and distribute their charge over multiple atoms. This stabilization can be achieved through the presence of double bonds or lone pairs of electrons.
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Hybridization: Consider the hybridization of the carbon atom that undergoes tautomerism. Generally, sp2 hybridized carbons are more stable than sp3 hybridized carbons. This is because sp2 hybridized carbons have a greater degree of pi bond character, which contributes to stability.
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Steric hindrance: Evaluate the presence of bulky groups near the carbon atom undergoing tautomerism. Bulky groups can create steric hindrance, which can destabilize the enol form.
By considering these factors, we can determine the most stable enol form during tautomerism.
Similar Questions
Which of the following statements does NOT correctly describe a keto-enol tautomerism?A.The reaction results in a pi bond migration, forming a C=C double bond.B.The reaction can be acid-catalyzed by protonating an enol oxygen atom.C.The reaction involves removal of a proton from an α-carbon.D.The reaction results in an equilibrium mixture of keto and enol tautomers, which are constitutional isomers.
3. Discuss the keto-enol tautomerism in the hydrolysis of phosphoenolpyruvate
What is keto-enol tautomerism of nucleic acids?
DARSHANCustom_Practice_Structural Isomerism_1310558 (CT1310558)OC21 min : 01 secQuestionNo.12(Single Correct) A+ A-Marks : 4.00/ 1.00Order of enol contents of the following compound is :-
What is tautomerisation?Select your answer:Select your answerOPTION ALTERNATIVE A 50:50 mix of enantiomers The formation of a ketone The formation of hemi-compounds The interconversion of two isomers None of the above
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