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QuestionNo.13(Single Correct) A+ A-Marks : 4.00/ 1.00Which of the following keto gives most stable enol during tautomerism ?

Question

QuestionNo.13(Single Correct) A+ A-Marks : 4.00/ 1.00Which of the following keto gives most stable enol during tautomerism ?

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Solution

To determine which keto form gives the most stable enol during tautomerism, we need to consider the factors that contribute to stability.

  1. Resonance: Look for keto forms that have resonance structures that stabilize the enol form. Resonance occurs when electrons can delocalize and distribute their charge over multiple atoms. This stabilization can be achieved through the presence of double bonds or lone pairs of electrons.

  2. Hybridization: Consider the hybridization of the carbon atom that undergoes tautomerism. Generally, sp2 hybridized carbons are more stable than sp3 hybridized carbons. This is because sp2 hybridized carbons have a greater degree of pi bond character, which contributes to stability.

  3. Steric hindrance: Evaluate the presence of bulky groups near the carbon atom undergoing tautomerism. Bulky groups can create steric hindrance, which can destabilize the enol form.

By considering these factors, we can determine the most stable enol form during tautomerism.

This problem has been solved

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