Which of the following geometries of complexes is indicated by Coordination number (CN) = 5?
Question
Which of the following geometries of complexes is indicated by Coordination number (CN) = 5?
Solution
The coordination number (CN) of a complex is the number of ligand (donor) atoms to which the central metal atom is directly connected.
For a coordination number of 5, the possible geometries of complexes are:
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Square Pyramidal: This geometry has a square base of four ligands with the fifth ligand forming the apex of the pyramid. The central metal atom is in the middle of the square base.
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Trigonal Bipyramidal: This geometry has a central metal atom surrounded by five ligands. Three of the ligands form an equilateral triangle in a plane, and the other two ligands are above and below this plane, forming the two 'poles' of the bipyramid.
So, the geometries of complexes indicated by Coordination number (CN) = 5 are Square Pyramidal and Trigonal Bipyramidal.
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