the first order chemical reaction
Question
the first order chemical reaction
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Solution
A first-order reaction is a reaction that proceeds at a rate that depends linearly on only one reactant concentration. Its rate law can be written as:
Rate = k[A]
where:
- Rate is the speed at which the reaction proceeds.
- k is the rate constant for the reaction.
- [A] is the concentration of a reactant.
The integrated rate law for a first-order reaction is:
ln([A]0/[A]) = kt
where:
- [A]0 is the initial concentration of the reactant.
- [A] is the concentration of the reactant at time t.
- k is the rate constant.
- t is the time.
The half-life of a first-order reaction, which is the time it takes for half of the reactant to be consumed, is independent of the initial concentration and can be calculated as:
t1/2 = 0.693/k
where:
- t1/2 is the half-life of the reaction.
- k is the rate constant.
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