Knowee
Questions
Features
Study Tools

An organic compound (A) reacts with PCl to produce another compound (B).(B) reacts withmagnesium metal in presence of ether to produce a Grignard reagent (C).(C) reacts with ethanal and theproduct is hydrolysed to produce propan-2-ol.Identify (A),(B) and (C) and explain the reactions

Question

An organic compound (A) reacts with PCl to produce another compound (B).(B) reacts withmagnesium metal in presence of ether to produce a Grignard reagent (C).(C) reacts with ethanal and theproduct is hydrolysed to produce propan-2-ol.Identify (A),(B) and (C) and explain the reactions

🧐 Not the exact question you are looking for?Go ask a question

Solution

(A) is an alcohol, specifically ethanol. (B) is ethyl chloride, and (C) is an ethylmagnesium chloride Grignard reagent.

Here are the reactions:

  1. Ethanol (A) reacts with PCl5 to produce ethyl chloride (B) and HCl. This is a substitution reaction where the -OH group in ethanol is replaced by a Cl atom.

    CH3CH2OH + PCl5 → CH3CH2Cl + HCl

  2. Ethyl chloride (B) reacts with magnesium metal in the presence of ether to produce an ethylmagnesium chloride Grignard reagent (C). This is a Grignard reaction, where the magnesium atom inserts itself between the carbon and the halogen in the alkyl halide.

    CH3CH2Cl + Mg → CH3CH2MgCl

  3. The Grignard reagent (C) reacts with ethanal to produce a tertiary alcohol. This is a nucleophilic addition reaction, where the Grignard reagent attacks the carbonyl carbon of the aldehyde.

    CH3CH2MgCl + CH3CHO → CH3CH(OH)CH3

  4. The product is then hydrolysed to produce propan-2-ol. This is a simple acid-base reaction, where the alkoxide ion (the conjugate base of the alcohol) is protonated by a water molecule to form the alcohol.

    CH3CH(OH)CH3 + H2O → CH3CH(OH)CH3 + OH-

This problem has been solved

Similar Questions

An organic compound A reacts with PCl3 to give B. The compound B with sodium metal in thepresence of dry ether and gives n-butane. Thus, A and 𝐵 are:

An organic compound (A) with molecular formula C2Cl3O2H is obtained when (B)reacts with Red P and Cl2. The organic compound (B) can be obtained on thereaction of methyl magnesium chloride with dry ice followed by acid hydrolysis.a. Identify A and B

(b) Give simple chemical test to distinguish between the following : (i) Ethanal and Propanone (ii) Phenol and Benzoic acid

Carboxylic acids can be prepared by treating a Grignard reagent with which of the following?Select answer from the options belowCarbonate ionAcetic anhydrideCarbon monoxideCarbon dioxide

2-bromopropane reacts with hot ethanolic sodium hydroxide.Which substance is the major product of this reaction?A propan-1-olB propan-2-olC 2-hydroxypropeneD propene

1/3

Upgrade your grade with Knowee

Get personalized homework help. Review tough concepts in more detail, or go deeper into your topic by exploring other relevant questions.