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hy is HCl not used to make the medium acidic in oxidation reactions of KMnO4 in acidic medium?

Question

hy is HCl not used to make the medium acidic in oxidation reactions of KMnO4 in acidic medium?

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Solution

The reason why HCl is not used to make the medium acidic in oxidation reactions of KMnO4 in acidic medium is because KMnO4 reacts with HCl to produce chlorine gas. This is an unwanted side reaction that can interfere with the main reaction and also poses a safety risk due to the toxicity of chlorine gas.

Here is the reaction:

2 KMnO4 + 16 HCl → 2 KCl + 2 MnCl2 + 8 H2O + 5 Cl2

Instead, sulfuric acid (H2SO4) is commonly used to acidify the solution in these reactions because it does not react with KMnO4.

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