What is the correct order of increasing boiling points?A. CH3CH3<CH3CH2Cl<CH3CH2Br<CH3CH2IB. CH3CH2Cl<CH3CH2Br<CH3CH3<CH3CH2IC. CH3CH2I<CH3CH2Br<CH3CH2Cl<CH3CH3D.
Question
What is the correct order of increasing boiling points?A. CH3CH3<CH3CH2Cl<CH3CH2Br<CH3CH2IB. CH3CH2Cl<CH3CH2Br<CH3CH3<CH3CH2IC. CH3CH2I<CH3CH2Br<CH3CH2Cl<CH3CH3D.
Solution
The correct order of increasing boiling points is based on the strength of the intermolecular forces. The stronger the intermolecular forces, the higher the boiling point.
The intermolecular forces in these molecules are London dispersion forces and dipole-dipole interactions.
-
London dispersion forces: These are present in all molecules and increase with the size and shape of the molecule. In this case, all molecules have similar sizes and shapes, so this factor does not significantly affect the boiling point.
-
Dipole-dipole interactions: These are present in polar molecules. In this case, all molecules are polar, but the strength of the dipole depends on the electronegativity of the atoms. Chlorine, bromine, and iodine are all more electronegative than carbon, but iodine is less electronegative than bromine, which is less electronegative than chlorine. Therefore, CH3CH2Cl has the strongest dipole-dipole interactions and CH3CH2I has the weakest.
Therefore, the correct order of increasing boiling points is CH3CH3<CH3CH2I<CH3CH2Br<CH3CH2Cl, which corresponds to option A.
Similar Questions
Arrange the following compounds in order of increasing boiling pointl.CH 3CH2CH2OHII.CH 3CH 2OHIII.CH3CH2CH2CH2OHIV. CH3CH 2CH2CH 2CH 3A. I < II < IV < IIIB. IV < III < II < IC. I < II < III < IVD. IV < I < II< III
Arrange following in increasing order of their boiling points ?A II > I > III > IV B II > III > I > IV C III > I > II > IV D II > IV > I > III
Which of the following compounds is expected to have the highest boilingpoint?Question 2Select one:a.CH3CH2CH3b.CH3CH2CH2CH3c.CH3OCH3d.CH3CH2OHe.CH3CH2F
Correct order of boiling points of the given liquids is:A. H2O > HF > HCl > NH3B. HF > H2O > HCl > NH3C. HF > H2O > NH3 > HClD. H2O > HF > NH3 > HCl
Which compound in each of the following pairs would have the higher boiling point ? Explain your answers.CH3CH2CH2OHorCH3CH2OCH3CH3CH2CH2OHorHOCH2CH2OH
Upgrade your grade with Knowee
Get personalized homework help. Review tough concepts in more detail, or go deeper into your topic by exploring other relevant questions.