An ore on treatment with dil. HCl gives the smell of rotten eggs. Name the type of this ore. Howcan metal be obtained from its concentrated ore ?
Question
An ore on treatment with dil. HCl gives the smell of rotten eggs. Name the type of this ore. Howcan metal be obtained from its concentrated ore ?
Solution
The ore that gives off the smell of rotten eggs when treated with dilute HCl is likely a sulfide ore. Sulfide ores contain sulfur as a major component, which is responsible for the rotten egg smell due to the release of hydrogen sulfide gas (H2S) when reacted with acid.
To obtain the metal from its concentrated ore, the following steps can be followed:
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Crushing and Grinding: The concentrated ore is first crushed into small pieces and then ground into a fine powder. This increases the surface area of the ore, making it easier for subsequent steps.
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Roasting: In some cases, the sulfide ore is roasted in the presence of excess oxygen. This converts the sulfide minerals into oxides, which are easier to process further.
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Smelting: The roasted ore is then mixed with a reducing agent, such as carbon or coke, and heated in a furnace. This process, known as smelting, helps to remove impurities and convert the metal oxide into its pure form.
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Refining: The obtained metal from smelting is often impure and needs further purification. This can be done through various methods such as electrolysis, fractional crystallization, or chemical precipitation, depending on the specific metal.
Overall, the process of obtaining the metal from its concentrated ore involves crushing, grinding, roasting, smelting, and refining.
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Ore is a naturally occuring rock found in Earth's crust that contains valuable minerals and metals. In an experiment, a researcher dissolved a sample of ore containing an unknown amount of iron in HCl(aq). The resulting aqueous solution, which contained both Fe2+(aq) and Fe3+(aq), was poured through a Jones reductor column containing Zn(Hg)(s) to convert all iron ions into a single oxidation state. The conversion of Fe3+(aq) to Fe2+(aq) in the Jones reductor column is shown in Figure 1.Figure 1 Jones reductor column used for the conversion of Fe3+(aq) to Fe2+(aq). The resulting Fe2+(aq) solution was collected using a syringe.To determine the total amount of iron in the sample, the Fe2+(aq) solution was then transferred to a container and titrated with 0.1 M K2Cr2O7(aq), which resulted in the conversion of Fe2+(aq) to Fe3+(aq) in an irreversible process. A reference electrode was used to monitor the solution potential as a function of K2Cr2O7(aq) volume added, and the equivalence point of the solution was reached after the addition of 9.50 mL of K2Cr2O7(aq). A schematic of the experimental setup is shown in Figure 2.Figure 2 Experimental setup for the titration of Fe2+(aq) with K2Cr2O7(aq) under acidic conditionsIn a second experiment, the researcher prepared another sample of Fe2+(aq) but used a 0.1 M I3−(aq) titrant solution instead of K2Cr2O7(aq).The standard reduction potentials for the species involved in the experiments are given in Table 1.Table 1 Standard reduction potentialsReduction half-reaction E°(V)Cr2O72−(aq) + 14 H+(aq) + 6 e− → 2 Cr3+(aq) + 7 H2O(l) +1.33Fe3+(aq) + e− → Fe2+(aq) +0.76I3−(aq) + 2 e− → 3 I−(aq) +0.53Zn2+(aq) + Hg(l) + 2 e− → Zn(Hg)(s) −0.76 Question 26Does the redox reaction between Cr2O72−(aq) and Fe2+(aq) require energy input?A.Yes; ∆G° = +2.09nF J/mol.B.Yes; ∆G° = +0.57nF J/mol.C.No; ∆G° = −0.57nF J/mol.D.No; ∆G° = −2.09nF J/mol.
An ore is a Blank 1 Question 8 that contains enough metal which can be economically extracted.
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