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Balance the following redox reaction that takes place in acidic solution: FeSO4(aq) + H2O2(aq) +   →   Fe2O3(aq) + SO42- (aq) +

Question

Balance the following redox reaction that takes place in acidic solution: FeSO4(aq) + H2O2(aq) +   →   Fe2O3(aq) + SO42- (aq) +

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Solution

Balancing a redox reaction involves balancing the oxidation and reduction half-reactions. Here are the steps:

  1. Identify the oxidation and reduction half-reactions. In this case, Fe2+ (from FeSO4) is oxidized to Fe3+ (in Fe2O3), and O2 (from H2O2) is reduced to O2- (in SO42- and Fe2O3).

  2. Balance the atoms other than O and H in each half-reaction. For the oxidation half-reaction, we have Fe2+ → Fe3+. For the reduction half-reaction, we have O2 → O2-.

  3. Balance the O atoms by adding H2O. For the oxidation half-reaction, no O atoms are present. For the reduction half-reaction, we add 3 H2O to the right side: O2 → 4 O2- + 6 H2O.

  4. Balance the H atoms by adding H+. For the oxidation half-reaction, no H atoms are present. For the reduction half-reaction, we add 12 H+ to the left side: O2 + 12 H+ → 4 O2- + 6 H2O.

  5. Balance the charge by adding electrons. For the oxidation half-reaction, we add 1 e- to the right side: Fe2+ → Fe3+ + e-. For the reduction half-reaction, we add 8 e- to the left side: O2 + 12 H+ + 8 e- → 4 O2- + 6 H2O.

  6. Multiply the half-reactions by factors that will make the number of electrons equal in both half-reactions. In this case, we multiply the oxidation half-reaction by 8 and the reduction half-reaction by 1.

  7. Add the half-reactions together and simplify to get the balanced redox reaction: 8 Fe2+ + O2 + 12 H+ → 8 Fe3+ + 4 O2- + 6 H2O.

  8. Convert the ions back to their original compounds to get the final balanced redox reaction: 8 FeSO4 + H2O2 + 12 H+ → 4 Fe2O3 + 8 SO42- + 6 H2O.

Please note that the balanced equation may not match the original equation exactly due to the addition of H+ ions, which are necessary to balance the equation in acidic solution.

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