Combustion occurs when an oxidation-reduction reaction takes place between a reduced fuel source and an oxidizer, most frequently oxygen. The reaction between hydrogen and oxygen forms water (Reaction 1) and is highly exothermic and thermodynamically favorable. At the completion of hydrogen combustion, essentially all H2 molecules have been converted to water. Nevertheless, at room temperature and atmospheric pressure, molecular hydrogen and oxygen can coexist quite stably.2 H2(g) + O2(g) → 2 H2O(g)Reaction 1A group of researchers designed two prototype internal combustion engines, each of which could inject a hydrogen/oxygen mixture into a 5-mL combustion chamber at a total pressure of 1 atm and could repeat this process for several cycles. In one engine design, a spark was generated to initiate combustion as hydrogen and oxygen were injected. In another method, the combustion chamber was coated with a small amount of platinum powder. Platinum dramatically increases the reaction rate at room temperature without the need for a spark. The platinum itself is not altered by the reaction and can be reused. Researchers measured the maximum power output of both engine designs under identical injection and temperature conditions (Figure 1).Figure 1 Relative power outputs of hydrogen engines with different ignition sources at 298 KThe power output of an engine is directly related to the rate of combustion. In the presence of platinum, researchers measured the engine's rate of water production at various temperatures and H2/O2 mixture compositions. The results are shown in Figure 2.Figure 2 Rate of combustion in platinum-coated engines under various conditionsAdapted from Schultze, M., Mantzaras, J. (2013) Hetero-/homogeneous combustion of hydrogen/air mixtures over platinum: Fuel-lean versus fuel-rich combustion modes. International Journal of Hydrogen Energy, Vol. 38, Issue 25, 10654-10670. Question 11Platinum most likely increases the reaction rate by stabilizing:A.the reactants.B.the products.C.the intermediate step.D.the transition state.
Question
Combustion occurs when an oxidation-reduction reaction takes place between a reduced fuel source and an oxidizer, most frequently oxygen. The reaction between hydrogen and oxygen forms water (Reaction 1) and is highly exothermic and thermodynamically favorable. At the completion of hydrogen combustion, essentially all H2 molecules have been converted to water. Nevertheless, at room temperature and atmospheric pressure, molecular hydrogen and oxygen can coexist quite stably.2 H2(g) + O2(g) → 2 H2O(g)Reaction 1A group of researchers designed two prototype internal combustion engines, each of which could inject a hydrogen/oxygen mixture into a 5-mL combustion chamber at a total pressure of 1 atm and could repeat this process for several cycles. In one engine design, a spark was generated to initiate combustion as hydrogen and oxygen were injected. In another method, the combustion chamber was coated with a small amount of platinum powder. Platinum dramatically increases the reaction rate at room temperature without the need for a spark. The platinum itself is not altered by the reaction and can be reused. Researchers measured the maximum power output of both engine designs under identical injection and temperature conditions (Figure 1).Figure 1 Relative power outputs of hydrogen engines with different ignition sources at 298 KThe power output of an engine is directly related to the rate of combustion. In the presence of platinum, researchers measured the engine's rate of water production at various temperatures and H2/O2 mixture compositions. The results are shown in Figure 2.Figure 2 Rate of combustion in platinum-coated engines under various conditionsAdapted from Schultze, M., Mantzaras, J. (2013) Hetero-/homogeneous combustion of hydrogen/air mixtures over platinum: Fuel-lean versus fuel-rich combustion modes. International Journal of Hydrogen Energy, Vol. 38, Issue 25, 10654-10670. Question 11Platinum most likely increases the reaction rate by stabilizing:A.the reactants.B.the products.C.the intermediate step.D.the transition state.
Solution
Platinum most likely increases the reaction rate by stabilizing:
D. the transition state.
Explanation: In the context of chemical reactions, catalysts like platinum work by providing an alternative reaction pathway with a lower activation energy. This is achieved by stabilizing the transition state, which is the highest energy configuration of the system during the reaction. By stabilizing the transition state, the catalyst lowers the energy barrier that needs to be overcome for the reaction to proceed, thus increasing the reaction rate.
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Unlike the combustion of organic, carbon-based matter such as wood, many explosives and pyrotechnic agents can be combusted underwater, within air-tight containers and in other hypoxic environments. Which of the following explains how a combustion reaction can occur in a hypoxic environment?A.The reaction occurs under adiabatic conditions and is not affected by lack of oxygen.B.Explosions are endothermic reactions that contain all the energy required to initialize combustion.C.The rapid rate at which an explosion occurs overcomes the need for atmospheric oxygen.D.Pyrotechnic agents contain their own oxidizer, so atmospheric oxygen is not required.
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