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Which is a stronger reducing agent Cr2+ or Fe2+ and why ?

Question

Which is a stronger reducing agent Cr2+ or Fe2+ and why ?

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Solution

The strength of a reducing agent is determined by its ability to lose electrons, or its reduction potential. The lower the reduction potential, the stronger the reducing agent.

Looking at the standard reduction potentials, we have:

Cr3+ + e- -> Cr2+ E° = -0.41 V Fe3+ + e- -> Fe2+ E° = +0.77 V

The reduction potential for the Cr3+/Cr2+ couple is lower than that for the Fe3+/Fe2+ couple, which means Cr2+ is a stronger reducing agent than Fe2+.

This is because Cr2+ is more eager to lose an electron to become Cr3+ compared to Fe2+ becoming Fe3+. Therefore, Cr2+ is a stronger reducing agent than Fe2+.

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