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Following two statements are providedStatement-I: Haloarenes (Ph-X where X is F/Cl/ Br/I) are deactivated for electrophilic substitution reactions.Statement-II: Haloalkanes (R-X where X is F/Cl/Br/I) are reactive for electrophilic substitution reactions.Select the correct option.Statement-I is true and statement-II is falseBoth statements-I and II are trueBoth statements-I and II are falseStatement-I is true and statement-II is correct explanation of statement-I

Question

Following two statements are providedStatement-I: Haloarenes (Ph-X where X is F/Cl/ Br/I) are deactivated for electrophilic substitution reactions.Statement-II: Haloalkanes (R-X where X is F/Cl/Br/I) are reactive for electrophilic substitution reactions.Select the correct option.Statement-I is true and statement-II is falseBoth statements-I and II are trueBoth statements-I and II are falseStatement-I is true and statement-II is correct explanation of statement-I

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Solution

The correct option is "Statement-I is true and statement-II is false".

Explanation:

Statement-I: Haloarenes (Ph-X where X is F/Cl/ Br/I) are deactivated for electrophilic substitution reactions. This statement is true. Haloarenes are less reactive towards electrophilic substitution reaction due to the electron withdrawing nature of the halogen atom. The halogen atom withdraws electrons from the benzene ring and makes it less electron-rich, thus decreasing its reactivity towards electrophilic substitution.

Statement-II: Haloalkanes (R-X where X is F/Cl/Br/I) are reactive for electrophilic substitution reactions. This statement is false. Haloalkanes are not typically reactive towards electrophilic substitution reactions. They are more reactive towards nucleophilic substitution reactions, where a nucleophile replaces the halogen atom.

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