It takes 614./kJmol to break a carbon-carbon double bond. Calculate the maximum wavelength of light for which a carbon-carbon double bond could be broken by absorbing a single photon.Be sure your answer has the correct number of significant digits.nm
Question
It takes 614./kJmol to break a carbon-carbon double bond. Calculate the maximum wavelength of light for which a carbon-carbon double bond could be broken by absorbing a single photon.Be sure your answer has the correct number of significant digits.nm
Solution
To solve this problem, we need to use the equation that relates energy, wavelength and Planck's constant:
E = h * c / λ
where: E is the energy per mole of photons, h is Planck's constant (6.626 x 10^-34 J*s), c is the speed of light (3.00 x 10^8 m/s), and λ is the wavelength.
We are given E in kJ/mol, but we need it in J/photon for the equation. To convert from kJ/mol to J/photon, we use Avogadro's number (6.022 x 10^23 mol^-1):
E = 614.4 kJ/mol * (10^3 J/kJ) / (6.022 x 10^23 mol^-1) = 1.02 x 10^-19 J/photon
Now we can solve for λ:
λ = h * c / E λ = (6.626 x 10^-34 J*s) * (3.00 x 10^8 m/s) / (1.02 x 10^-19 J/photon) λ = 1.94 x 10^-7 m
Since the question asks for the answer in nm, we convert from m to nm:
λ = 1.94 x 10^-7 m * (10^9 nm/m) = 194 nm
So, the maximum wavelength of light for which a carbon-carbon double bond could be broken by absorbing a single photon is 194 nm.
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