Which of the following will not give HVZ reaction?Trichloroethanoic acid2-methyl butanoic acidEthanoic acidPropanoic acid
Question
Which of the following will not give HVZ reaction?Trichloroethanoic acid2-methyl butanoic acidEthanoic acidPropanoic acid
Solution
The Hell-Volhard-Zelinsky (HVZ) reaction involves the alpha substitution of a carboxylic acid by a halogen. This reaction requires an alpha hydrogen in the carboxylic acid.
Looking at the options:
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Trichloroethanoic acid: This compound has no alpha hydrogens because all the hydrogens of the alpha carbon are substituted by chlorine atoms. Therefore, it cannot undergo HVZ reaction.
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2-methyl butanoic acid: This compound has alpha hydrogens and can undergo HVZ reaction.
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Ethanoic acid: This compound has alpha hydrogens and can undergo HVZ reaction.
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Propanoic acid: This compound has alpha hydrogens and can undergo HVZ reaction.
So, the compound that will not give HVZ reaction is Trichloroethanoic acid.
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