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Which of the following will not give HVZ reaction?Trichloroethanoic acid2-methyl butanoic acidEthanoic acidPropanoic acid

Question

Which of the following will not give HVZ reaction?Trichloroethanoic acid2-methyl butanoic acidEthanoic acidPropanoic acid

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Solution

The Hell-Volhard-Zelinsky (HVZ) reaction involves the alpha substitution of a carboxylic acid by a halogen. This reaction requires an alpha hydrogen in the carboxylic acid.

Looking at the options:

  1. Trichloroethanoic acid: This compound has no alpha hydrogens because all the hydrogens of the alpha carbon are substituted by chlorine atoms. Therefore, it cannot undergo HVZ reaction.

  2. 2-methyl butanoic acid: This compound has alpha hydrogens and can undergo HVZ reaction.

  3. Ethanoic acid: This compound has alpha hydrogens and can undergo HVZ reaction.

  4. Propanoic acid: This compound has alpha hydrogens and can undergo HVZ reaction.

So, the compound that will not give HVZ reaction is Trichloroethanoic acid.

This problem has been solved

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