Which of the following is used to convert an alcohol to a carboxylic acid?Select answer from the options belowPyridinium chlorochromateROH, pyridineSodium cyanideSodium dichromate, sulfuric acid, and waterSave for LaterSubmit Answer
Question
Which of the following is used to convert an alcohol to a carboxylic acid?Select answer from the options belowPyridinium chlorochromateROH, pyridineSodium cyanideSodium dichromate, sulfuric acid, and waterSave for LaterSubmit Answer
Solution
The correct answer is Sodium dichromate, sulfuric acid, and water. This combination is commonly used in the oxidation of alcohols to carboxylic acids. Here's a step-by-step explanation:
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Sodium dichromate (Na2Cr2O7) is a strong oxidizing agent. It is often used in combination with sulfuric acid (H2SO4) to create an acidic environment for the reaction.
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The alcohol (R-OH) is protonated by the sulfuric acid, creating a good leaving group (water).
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The chromium(VI) species produced by sodium dichromate then oxidizes the alcohol to a carbonyl compound (either an aldehyde or a ketone, depending on whether the starting alcohol was primary or secondary).
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If the conditions are sufficiently acidic and the temperature is high enough, the carbonyl compound can be further oxidized to a carboxylic acid.
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Water is often included in the reaction mixture to ensure that the reaction medium remains acidic throughout the process.
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