Simple aliphatic carboxylic acids upto four carbon atoms are miscible in water due to the formation of hydrogen bond with water.Statement-II : The simplest aromatic carboxylic acid is nearly insoluble in cold water.A Statement-I and II both are correct. B Statement-I is incorrect but statement-II is correct. C Statement-I is correct but statement-II is false. D Both statement-I and II are incorrect.
Question
Simple aliphatic carboxylic acids upto four carbon atoms are miscible in water due to the formation of hydrogen bond with water.Statement-II : The simplest aromatic carboxylic acid is nearly insoluble in cold water.A Statement-I and II both are correct. B Statement-I is incorrect but statement-II is correct. C Statement-I is correct but statement-II is false. D Both statement-I and II are incorrect.
Solution
Statement-I: Simple aliphatic carboxylic acids up to four carbon atoms are miscible in water due to the formation of hydrogen bonds with water.
Explanation:
- Simple aliphatic carboxylic acids refer to carboxylic acids that have a straight chain of carbon atoms and no other functional groups.
- These carboxylic acids have a polar functional group called the carboxyl group (-COOH), which can form hydrogen bonds with water molecules.
- The formation of hydrogen bonds between the carboxylic acid and water molecules allows for the molecules to mix and dissolve in water.
- Therefore, statement-I is correct.
Statement-II: The simplest aromatic carboxylic acid is nearly insoluble in cold water.
Explanation:
- Aromatic carboxylic acids are carboxylic acids that have an aromatic ring attached to the carboxyl group.
- The simplest aromatic carboxylic acid is benzoic acid (C6H5COOH).
- Due to the presence of the aromatic ring, benzoic acid is less polar compared to aliphatic carboxylic acids.
- The lower polarity of benzoic acid makes it less likely to form hydrogen bonds with water molecules.
- As a result, benzoic acid is nearly insoluble in cold water.
- Therefore, statement-II is correct.
Based on the explanations provided, the correct answer is option B: Statement-I is incorrect, but statement-II is correct.
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