Which of the following atoms or groups migrate most rapidly during a Baeyer-Villiger oxidation?Select answer from the options belowPhenylMethylHydrogen1º Carbon3º Carbon2º CarbonSave for LaterSubmit Answer
Question
Which of the following atoms or groups migrate most rapidly during a Baeyer-Villiger oxidation?Select answer from the options belowPhenylMethylHydrogen1º Carbon3º Carbon2º CarbonSave for LaterSubmit Answer
Solution
In a Baeyer-Villiger oxidation, the migrating group is determined by migratory aptitude. The general order of migratory aptitude is tertiary carbon > secondary carbon > primary carbon > methyl > hydrogen. Therefore, the 3º Carbon (tertiary carbon) would migrate most rapidly during a Baeyer-Villiger oxidation.
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