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Which of these reactions proceeds by a free radical mechanism in the presence of UV light?A.     C6H6 + Cl2 → C6H5Cl + HClB.     C6H6 + 3H2 → C6H12C.     CH2CH2 + HBr → CH3CH2BrD.     CH3CH3 + Cl2 → CH3CH2Cl + HCl

Question

Which of these reactions proceeds by a free radical mechanism in the presence of UV light?A.     C6H6 + Cl2 → C6H5Cl + HClB.     C6H6 + 3H2 → C6H12C.     CH2CH2 + HBr → CH3CH2BrD.     CH3CH3 + Cl2 → CH3CH2Cl + HCl

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Solution

The reaction that proceeds by a free radical mechanism in the presence of UV light is D. CH3CH3 + Cl2 → CH3CH2Cl + HCl.

Here's a step-by-step explanation:

  1. The reaction starts with the homolytic cleavage of the Cl-Cl bond in the presence of UV light, which results in the formation of two chlorine free radicals.

  2. These chlorine free radicals are very reactive and can abstract a hydrogen atom from the ethane (CH3CH3) molecule, forming a new H-Cl bond and leaving behind an ethyl free radical (CH3CH2•).

  3. The ethyl free radical can then react with another molecule of Cl2, forming a new C-Cl bond and another chlorine free radical.

  4. This chlorine free radical can then go on to react with another ethane molecule, and the process repeats. This is known as a chain reaction.

This type of reaction is characteristic of free radical halogenation, which is a common type of reaction that proceeds via a free radical mechanism.

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Similar Questions

Which of these reactions proceeds by a free radical mechanism in the presence of UV light?

What is the mechanism of the reaction between ethane and chlorine in sunlight?A.  Free radical substitutionB.  Free radical additionC.  Electrophilic substitutionD.  Electrophilic addition

Which of the following is carrying energized electrons produced by the light reactions?Group of answer choicesNADP⁺NADHNAD⁺G3PNADPHchlorophyll bchlorophyll a

What would be the major product of the following reaction?C6H5 -CH2-OC6H5 + HBr  A + B

Which molecule is the source of electrons for the light reactions?CO2C6H12O6NADPHH2O

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