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Which conclusion is most reasonable given the MO diagrams for benzene and cyclobutadiene?A.Electrons in antibonding MOs increase a molecule’s energy.B.Nonbonding MOs are lower in energy than the atomic orbitals from which they form.C.In aromatic molecules, nonbonding MOs are lower in energy than bonding MOs.D.Partially filled antibonding MOs increase a molecule’s stability.

Question

Which conclusion is most reasonable given the MO diagrams for benzene and cyclobutadiene?A.Electrons in antibonding MOs increase a molecule’s energy.B.Nonbonding MOs are lower in energy than the atomic orbitals from which they form.C.In aromatic molecules, nonbonding MOs are lower in energy than bonding MOs.D.Partially filled antibonding MOs increase a molecule’s stability.

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Solution

The most reasonable conclusion given the MO diagrams for benzene and cyclobutadiene is A. Electrons in antibonding MOs increase a molecule’s energy.

Here's why:

Molecular Orbital (MO) theory explains that in a molecule, electrons are not assigned to individual bonds between atoms, but are moving under the influence of the nuclei in the whole molecule. The MO diagram represents the energy levels of these molecular orbitals.

In the MO diagram, bonding MOs are at a lower energy level than the atomic orbitals from which they form, while antibonding MOs are at a higher energy level. This is because when a bond forms, it is more stable and thus lower in energy. Conversely, antibonding MOs are less stable and higher in energy.

When electrons are in antibonding MOs, they are at a higher energy level, which means the molecule's overall energy is increased. This makes the molecule less stable. Therefore, conclusion A is the most reasonable.

The other options are not typically true. Nonbonding MOs are not necessarily lower in energy than the atomic orbitals from which they form (B). In aromatic molecules, nonbonding MOs are not lower in energy than bonding MOs (C). And partially filled antibonding MOs do not increase a molecule’s stability, they actually decrease it (D).

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