what happens when benzene is treated with Br2 in presence of anhydrous AlCl3
Question
what happens when benzene is treated with Br2 in presence of anhydrous AlCl3
Solution
When benzene is treated with bromine (Br2) in the presence of anhydrous aluminium chloride (AlCl3), a substitution reaction occurs. This reaction is known as electrophilic aromatic substitution. Here are the steps:
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Generation of Electrophile: The first step is the generation of the electrophile. Bromine (Br2) reacts with anhydrous AlCl3 to form a complex, which is a powerful electrophile. The reaction is as follows: Br2 + AlCl3 → [Br-Br]+AlCl4-
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Formation of sigma complex: The electrophile [Br-Br]+ then attacks the benzene ring to form a sigma complex. This step involves the breaking of the aromaticity of the benzene ring.
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Deprotonation: The sigma complex then loses a proton to the AlCl4- ion to regenerate the AlCl3 catalyst and restore the aromaticity of the benzene ring. The final product is bromobenzene.
So, the overall reaction is: C6H6 + Br2 → C6H5Br + HBr in the presence of AlCl3.
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