What can be said about a reaction with H = 620 kJ/mol and S = -0.46 kJ/(molK)?A.It is spontaneous above 1347 K.B.It is spontaneous at 298 K.C.It is never spontaneous.D.It is always spontaneous.SUBMITarrow_backPREVIOUS
Question
What can be said about a reaction with H = 620 kJ/mol and S = -0.46 kJ/(molK)?A.It is spontaneous above 1347 K.B.It is spontaneous at 298 K.C.It is never spontaneous.D.It is always spontaneous.SUBMITarrow_backPREVIOUS
Solution
The spontaneity of a reaction can be determined using the Gibbs Free Energy equation, which is ΔG = ΔH - TΔS.
In this case, ΔH (change in enthalpy) is 620 kJ/mol and ΔS (change in entropy) is -0.46 kJ/(molK).
For a reaction to be spontaneous, ΔG must be less than 0.
Let's calculate the temperature at which ΔG = 0, because above this temperature, the reaction will be spontaneous.
0 = 620 kJ/mol - T * -0.46 kJ/(molK)
Rearranging the equation gives:
T = 620 kJ/mol / 0.46 kJ/(molK) = 1347.83 K
Therefore, the reaction is spontaneous above 1347.83 K.
So, the correct answer is A. It is spontaneous above 1347 K.
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