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Derive the condition of pressure and temperature at which real gas will behave asideal gas.

Question

Derive the condition of pressure and temperature at which real gas will behave asideal gas.

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Solution

The behavior of real gases deviates from ideal gas behavior due to intermolecular interactions and the finite size of gas particles. However, under certain conditions, real gases can behave like ideal gases. These conditions are derived from the ideal gas law and the van der Waals equation, which accounts for the behavior of real gases.

  1. The ideal gas law is PV = nRT, where P is the pressure, V is the volume, n is the number of moles, R is the ideal gas constant, and T is the temperature.

  2. The van der Waals equation is [P + a(n/V)^2] * [V - nb] = nRT, where a and b are constants that account for intermolecular interactions and the finite size of gas particles, respectively.

  3. For a real gas to behave like an ideal gas, the terms a(n/V)^2 and nb in the van der Waals equation must be negligible.

  4. The term a(n/V)^2 becomes negligible when the pressure is low. This is because at low pressures, the volume of the gas is large, so the density of gas particles (n/V) is low. As a result, intermolecular interactions are minimal.

  5. The term nb becomes negligible when the temperature is high. This is because at high temperatures, the kinetic energy of the gas particles is high, so they move around a lot and occupy a larger volume. As a result, the finite size of the gas particles becomes less significant.

  6. Therefore, the condition under which a real gas behaves like an ideal gas is at low pressure and high temperature.

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