Which of the following alkynes cannot be efficiently prepared by alkylation(s) of acetylene?Select answer from the options below4-methyl-2-octyne5-methyl-2-octyne2-octyne1-octyne
Question
Which of the following alkynes cannot be efficiently prepared by alkylation(s) of acetylene?Select answer from the options below4-methyl-2-octyne5-methyl-2-octyne2-octyne1-octyne
Solution
The alkyne that cannot be efficiently prepared by alkylations of acetylene is 1-octyne.
Here's why:
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Alkylation of acetylene involves the addition of alkyl groups to the acetylene molecule.
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The process typically occurs at the terminal carbon of the acetylene molecule, which is less substituted and more accessible for the reaction.
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Therefore, alkynes with substitutions at the internal carbons (like 4-methyl-2-octyne, 5-methyl-2-octyne, and 2-octyne) can be prepared by this method.
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However, 1-octyne, which has the substitution at the terminal carbon, cannot be efficiently prepared by alkylation of acetylene because the terminal carbon is already substituted.
So, the correct answer is 1-octyne.
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