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18 gm of ice is converted into water at 0°C and 1 atm. The entropies of  and  are 38.2 and 60 J/mol K respectively. The enthalpy change for this conversion is :

Question

18 gm of ice is converted into water at 0°C and 1 atm. The entropies of  and  are 38.2 and 60 J/mol K respectively. The enthalpy change for this conversion is :

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Solution

The enthalpy change for the conversion of ice into water can be calculated using the formula:

ΔH = ΔS * T

where: ΔH is the enthalpy change, ΔS is the entropy change, and T is the temperature.

First, we need to calculate the entropy change (ΔS). The entropy of water is greater than the entropy of ice, so the entropy change is positive. We subtract the entropy of ice from the entropy of water:

ΔS = S_water - S_ice = 60 J/mol K - 38.2 J/mol K = 21.8 J/mol K

Next, we convert the temperature from Celsius to Kelvin. The temperature is 0°C, which is equivalent to 273.15 K.

Finally, we substitute these values into the formula to find the enthalpy change:

ΔH = ΔS * T = 21.8 J/mol K * 273.15 K = 5956.47 J/mol

However, the question states that we have 18 gm of ice. The molar mass of water (and ice) is approximately 18 gm/mol, so we have 1 mol of ice. Therefore, the enthalpy change for this conversion is 5956.47 J/mol * 1 mol = 5956.47 J.

This problem has been solved

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