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Four mixtures are added to four separate 50 cm 3 samples of water and stirred.Which mixture results in a solution with the highest pH?201.0 g of aluminium oxide and 1.0 g of aluminium chlorideA1.0 g of magnesium oxide and 1.0 g of magnesium chlorideB1.0 g of phosphorus oxide and 1.0 g of phosphorus chlorideC1.0 g of silicon dioxide and 1.0 g of silicon chloride

Question

Four mixtures are added to four separate 50 cm 3 samples of water and stirred.Which mixture results in a solution with the highest pH?201.0 g of aluminium oxide and 1.0 g of aluminium chlorideA1.0 g of magnesium oxide and 1.0 g of magnesium chlorideB1.0 g of phosphorus oxide and 1.0 g of phosphorus chlorideC1.0 g of silicon dioxide and 1.0 g of silicon chloride

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Solution

To answer this question, we need to understand the nature of the substances involved.

  1. Aluminium oxide is amphoteric (can act as both acid and base) and aluminium chloride is acidic.
  2. Magnesium oxide is basic and magnesium chloride is slightly acidic.
  3. Phosphorus oxide is acidic and phosphorus chloride is also acidic.
  4. Silicon dioxide is weakly acidic and silicon chloride is acidic.

A solution's pH is determined by the concentration of hydrogen ions (H+) it contains. The more H+ ions, the more acidic the solution is and the lower its pH. Conversely, the fewer H+ ions (meaning more hydroxide ions, OH-), the more basic or alkaline the solution is and the higher its pH.

Given this, the mixture that would result in a solution with the highest pH (most basic or alkaline) would be the one with the most basic substances and the least acidic substances.

In this case, that would be mixture B (1.0 g of magnesium oxide and 1.0 g of magnesium chloride) because magnesium oxide is basic and magnesium chloride is only slightly acidic.

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