The arenium ion which is not involved in the bromination of Aniline is
Question
The arenium ion which is not involved in the bromination of Aniline is
Solution
The arenium ion which is not involved in the bromination of Aniline is the meta-arenium ion.
Here's why:
-
Aniline is an aromatic compound with an amino group (-NH2) attached to the benzene ring.
-
In the bromination of aniline, the amino group (-NH2) is a strong activating group. This means it increases the electron density of the benzene ring, making it more susceptible to electrophilic attack.
-
The increased electron density is particularly located at the ortho and para positions of the benzene ring (relative to the -NH2 group). This is because the -NH2 group can donate electron density to the benzene ring through resonance, and these are the positions that the resonance structures indicate would have the most electron density.
-
Therefore, when bromination occurs, the bromine is most likely to attach at the ortho or para position, forming an ortho- or para-arenium ion.
-
The meta-arenium ion, on the other hand, would involve bromination at the meta position, which is not favored because this position does not have increased electron density from the -NH2 group. Therefore, the meta-arenium ion is not involved in the bromination of aniline.
Similar Questions
Anisole undergoes bromination with bromine in ethanoic acid even in the absence of iron (III)bromide catalyst(a) Due to the activation of benzene ring by the methoxy group.(b) Due to the de-activation of benzene ring by the methoxy group.(c) Due to the increase in electron density at ortho and para positions(d) Due to the formation of stable carbocation.
Why is aniline less basic than ammonia ?Explain
Aniline to chlorobenzene
tert-Butyl bromide reacts with aq.NaOH by S mechanism while n-butyl bromide reacts by Smechanism. Why?
An ionic compound made up of a cation from a base and an anion from an acid is a(n)
Upgrade your grade with Knowee
Get personalized homework help. Review tough concepts in more detail, or go deeper into your topic by exploring other relevant questions.